In today's world, Sulfate mineral has gained unprecedented relevance. Since its emergence, Sulfate mineral has impacted fundamental aspects of society, economy and culture. In this article, we will explore in depth the role of Sulfate mineral in the current context, analyzing its causes, consequences and possible solutions. Through different perspectives and case studies, we will seek to understand the reach and influence of Sulfate mineral in various fields, as well as its potential to transform the world in the future.
Class of minerals that include the sulfate ion
The sulfate minerals are a class of minerals that include the sulfate ion (SO2− 4 ) within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments , as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits. The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.[ 1]
Anhydrite crystal structure
Barite with cerussite
Sulfate minerals include:
Anhydrous sulfates
Hydroxide and hydrous sulfates
Nickel–Strunz classification -07- sulfates
Hanksite, one of the rare minerals that is a sulfate and carbonate
IMA -CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the Classification of Nickel–Strunz (mindat.org , 10 ed, pending publication).
Abbreviations:
"*" – discredited (IMA/CNMNC status).
"?" – questionable/doubtful (IMA/CNMNC status).
"REE" – Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)
"PGE" – Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt)
03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V Vanadates), 09 Silicates:
Neso: insular (from Greek νησος nēsos, island)
Soro: grouping (from Greek σωροῦ sōros, heap, mound (especially of corn))
Cyclo: ring
Ino: chain (from Greek ις , fibre)
Phyllo: sheet (from Greek φύλλον phyllon , leaf)
Tekto: three-dimensional framework
Nickel–Strunz code scheme: NN.XY.##x
NN: Nickel–Strunz mineral class number
X: Nickel–Strunz mineral division letter
Y: Nickel–Strunz mineral family letter
##x: Nickel–Strunz mineral/group number, x add-on letter
Class: sulfates, selenates, tellurates
07.A Sulfates (selenates, etc.) without Additional Anions, without H2 O
07.AB With medium-sized cations: 05 Millosevichite , 05 Mikasaite ; 10 Chalcocyanite , 10 Zincosite *
07.AC With medium-sized and large cations: IMA2008-029, 05 Vanthoffite ; 10 Efremovite , 10 Manganolangbeinite , 10 Langbeinite ; 15 Eldfellite , 15 Yavapaiite ; 20 Godovikovite , 20 Sabieite ; 25 Thenardite , 35 Aphthitalite
07.AD With only large cations: 05 Arcanite , 05 Mascagnite ; 10 Mercallite , 15 Misenite , 20 Letovicite , 25 Glauberite , 30 Anhydrite ; 35 Anglesite , 35 Barite , 35 Celestine , 35 Radiobarite *, 35 Olsacherite ; 40 Kalistrontite , 40 Palmierite
07.B Sulfates (selenates, etc.) with additional anions, without H2 O
07.BB With medium-sized cations: 05 Caminite , 10 Hauckite , 15 Antlerite , 20 Dolerophanite , 25 Brochantite , 30 Vergasovaite , 35 Klebelsbergite , 40 Schuetteite , 45 Paraotwayite , 50 Xocomecatlite , 55 Pauflerite
07.BC With medium-sized and large cations: 05 Dansite ; 10 Alunite , 10 Ammonioalunite , 10 Ammoniojarosite , 10 Beaverite , 10 Argentojarosite , 10 Huangite , 10 Dorallcharite , 10 Jarosite , 10 Hydroniumjarosite , 10 Minamiite , 10 Natrojarosite , 10 Natroalunite , 10 Osarizawaite , 10 Plumbojarosite , 10 Walthierite , 10 Schlossmacherite ; 15 Yeelimite ; 20 Atlasovite , 20 Nabokoite ; 25 Chlorothionite ; 30 Fedotovite , 30 Euchlorine ; 35 Kamchatkite , 40 Piypite ; 45 Klyuchevskite-Duplicate, 45 Klyuchevskite , 45 Alumoklyuchevskite ; 50 Caledonite , 55 Wherryite , 60 Mammothite ; 65 Munakataite , 65 Schmiederite , 65 Linarite ; 70 Chenite , 75 Krivovichevite
07.BD With only large cations: 05 Sulphohalite ; 10 Galeite , 10 Schairerite ; 15 Kogarkoite ; 20 Cesanite , 20 Caracolite ; 25 Burkeite , 30 Hanksite , 35 Cannonite , 40 Lanarkite , 45 Grandreefite , 50 Itoite , 55 Chiluite , 60 Hectorfloresite , 65 Pseudograndreefite , 70 Sundiusite
07.C Sulfates (selenates, etc.) without additional anions, with H2 O
07.CB With only medium-sized cations: 05 Gunningite , 05 Dwornikite , 05 Kieserite , 05 Szomolnokite , 05 Szmikite , 05 Poitevinite , 05 Cobaltkieserite ; 07 Sanderite , 10 Bonattite , 15 Boyleite , 15 Aplowite , 15 Ilesite , 15 Rozenite , 15 Starkeyite , 15 IMA2002-034; 20 Chalcanthite , 20 Jokokuite , 20 Pentahydrite , 20 Siderotil ; 25 Bianchite , 25 Ferrohexahydrite , 25 Chvaleticeite , 25 Hexahydrite , 25 Moorhouseite , 25 Nickelhexahydrite ; 30 Retgersite ; 35 Bieberite , 35 Boothite , 35 Mallardite , 35 Melanterite , 35 Zincmelanterite , 35 Alpersite ; 40 Epsomite , 40 Goslarite , 40 Morenosite ; 45 Alunogen , 45 Meta-alunogen ; 50 Coquimbite , 50 Paracoquimbite ; 55 Rhomboclase , 60 Kornelite , 65 Quenstedtite , 70 Lausenite ; 75 Lishizhenite , 75 Romerite ; 80 Ransomite ; 85 Bilinite , 85 Apjohnite , 85 Dietrichite , 85 Halotrichite , 85 Pickeringite , 85 Redingtonite , 85 Wupatkiite ; 90 Meridianiite , 95 Caichengyunite
07.CC With medium-sized and large cations: 05 Krausite , 10 Tamarugite ; 15 Mendozite , 15 Kalinite ; 20 Lonecreekite , 20 Alum-(K) , 20 Alum-(Na) , 20 Lanmuchangite , 20 Tschermigite ; 25 Pertlikite , 25 Monsmedite ?, 25 Voltaite , 25 Zincovoltaite ; 30 Krohnkite , 35 Ferrinatrite , 40 Goldichite , 45 Loweite ; 50 Blodite , 50 Changoite , 50 Nickelblodite ; 55 Mereiterite , 55 Leonite ; 60 Boussingaultite , 60 Cyanochroite , 60 Mohrite , 60 Picromerite , 60 Nickelboussingaultite ; 65 Polyhalite ; 70 Leightonite , 75 Amarillite , 80 Konyaite , 85 Wattevilleite
07.CD With only large cations: 05 Matteuccite , 10 Mirabilite , 15 Lecontite , 20 Hydroglauberite , 25 Eugsterite , 30 Gorgeyite ; 35 Koktaite , 35 Syngenite ; 40 Gypsum , 45 Bassanite , 50 Zircosulfate , 55 Schieffelinite , 60 Montanite , 65 Omongwaite
07.D Sulfates (selenates, etc.) with additional anions, with H2 O
07.DB With only medium-sized cations; insular octahedra and finite groups: 05 Svyazhinite , 05 Aubertite , 05 Magnesioaubertite ; 10 Rostite , 10 Khademite ; 15 Jurbanite ; 20 Minasragrite , 20 Anorthominasragrite , 20 Orthominasragrite ; 25 Bobjonesite ; 30 Amarantite , 30 Hohmannite , 30 Metahohmannite ; 35 Aluminocopiapite , 35 Copiapite , 35 Calciocopiapite , 35 Cuprocopiapite , 35 Ferricopiapite , 35 Magnesiocopiapite , 35 Zincocopiapite
07.DC With only medium-sized cations; chains of corner-sharing octahedra: 05 Aluminite , 05 Meta-aluminite ; 10 Butlerite , 10 Parabutlerite ; 15 Fibroferrite , 20 Xitieshanite ; 25 Botryogen , 25 Zincobotryogen ; 30 Chaidamuite , 30 Guildite
07.DD With only medium-sized cations; sheets of edge-sharing octahedra: 05 Basaluminite ?, 05 Felsobanyaite , 07.5 Kyrgyzstanite , 08.0 Zn-Schulenbergite ; 10 Langite , 10 Posnjakite , 10 Wroewolfeite ; 15 Spangolite , 20 Ktenasite , 25 Christelite ; 30 Campigliaite , 30 Devilline , 30 Orthoserpierite , 30 Niedermayrite , 30 Serpierite ; 35 Motukoreaite , 35 Mountkeithite , 35 Glaucocerinite , 35 Honessite , 35 Hydrowoodwardite , 35 Hydrohonessite , 35 Shigaite , 35 Natroglaucocerinite , 35 Wermlandite , 35 Nikischerite , 35 Zincaluminite , 35 Woodwardite , 35 Carrboydite , 35 Zincowoodwardite , 35 Zincowoodwardite-3R, 35 Zincowoodwardite-1T; 40 Lawsonbauerite , 40 Torreyite , 45 Mooreite , 50 Namuwite , 55 Bechererite , 60 Ramsbeckite , 65 Vonbezingite , 70 Redgillite ; 75 Chalcoalumite , 75 Nickelalumite *; 80 Guarinoite , 80 Theresemagnanite , 80 Schulenbergite ; 85 Montetrisaite
07.DE With only medium-sized cations; unclassified: 05 Mangazeite ; 10 Carbonatecyanotrichite , 10 Cyanotrichite ; 15 Schwertmannite , 20 Tlalocite , 25 Utahite , 35 Coquandite , 40 Osakaite , 45 Wilcoxite , 50 Stanleyite , 55 Mcalpineite , 60 Hydrobasaluminite , 65 Zaherite , 70 Lautenthalite , 75 Camérolaite , 80 Brumadoite
07.DF With large and medium-sized cations: 05 Uklonskovite , 10 Kainite , 15 Natrochalcite ; 20 Metasideronatrite , 20 Sideronatrite ; 25 Despujolsite , 25 Fleischerite , 25 Schaurteite , 25 Mallestigite ; 30 Slavikite , 35 Metavoltine ; 40 Lannonite , 40 Vlodavetsite ; 45 Peretaite , 50 Gordaite , 55 Clairite , 60 Arzrunite , 65 Elyite , 70 Yecoraite , 75 Riomarinaite , 80 Dukeite , 85 Xocolatlite
07.DG With large and medium-sized cations; with NO3 , CO3 , B(OH)4 , SiO4 or IO3 : 05 Darapskite ; 10 Clinoungemachite , 10 Ungemachite , 10 Humberstonite ; 15 Bentorite , 15 Charlesite , 15 Ettringite , 15 Jouravskite , 15 Sturmanite , 15 Thaumasite , 15 Carraraite , 15 Buryatite ; 20 Rapidcreekite , 25 Tatarskite , 30 Nakauriite , 35 Chessexite ; 40 Carlosruizite , 40 Fuenzalidaite ; 45 Chelyabinskite *
07.E Uranyl Sulfates
07.EA Without cations: 05 Uranopilite , 05 Metauranopilite , 10 Jachymovite
07.EB With medium-sized cations: 05 Johannite , 10 Deliensite
07.EC With medium-sized and large cations: 05 Cobaltzippeite , 05 Magnesiozippeite , 05 Nickelzippeite , 05 Natrozippeite , 05 Zinc-zippeite , 05 Zippeite ; 10 Rabejacite , 15 Marecottite , 20 Pseudojohannite
07.J Thiosulfates
07.X Unclassified Strunz Sulfates (Selenates, Tellurates)
Class: chromates
07.F Chromates
07.FA Without additional anions: 05 Tarapacaite , 10 Chromatite , 15 Hashemite , 20 Crocoite
07.FB With additional O, V, S, Cl: 05 Phoenicochroite , 10 Santanaite , 15 Wattersite , 20 Deanesmithite , 25 Edoylerite
07.FC With PO4 , AsO4 , SiO4 : 05 Vauquelinite ; 10 Fornacite , 10 Molybdofornacite ; 15 Hemihedrite , 15 Iranite ; 20 Embreyite , 20 Cassedanneite ;
07.FD Dichromates: 05 Lópezite
Class: molybdates, wolframates and niobates
07.G Molybdates, wolframates and niobates
07.GA Without additional anions or H2 O: 05 Fergusonite -(Ce), 05 Fergusonite-(Nd)N , 05 Fergusonite-(Y), 05 Powellite , 05 Wulfenite , 05 Stolzite , 05 Scheelite ; 10 Formanite-(Y) , 10 Iwashiroite-(Y) ; 15 Paraniite-(Y)
07.GB With additional anions and/or H2 O: 05 Lindgrenite , 10 Szenicsite , 15 Cuprotungstite , 20 Phyllotungstite , 25 Rankachite , 30 Ferrimolybdite , 35 Anthoinite , 35 Mpororoite , 40 Obradovicite -KCu, 45 Mendozavilite -NaFe, 45 Paramendozavilite , 50 Tancaite -(Ce)
07.H Uranium and uranyl molybdates and wolframates
References
^ Klein, Cornelis and Cornelius S. Hurlbut, 1985, Manual of Mineralogy, 20th ed., John Wiley and Sons, New York, pp. 347–354 ISBN 0-471-80580-7 .
"Special cases" ("native elements and organic minerals") "Sulfides and oxides"
Sulfides (IDs 2.A–F)
Sulfosalts ; sulfarsenites, sulfantimonites, sulfbismuthites (IDs 2.G)
Sulfosalts; sulfarsenates, sulfantimonates (IDs 2.K)
Other sulfosalts (IDs 2.H–J and 2.L–M)
Tellurium oxysalts
Vanadium oxides (IDs 4.H)
"Evaporites and similars" "Mineral structures with tetrahedral units" (sulfate anion, phosphate anion, silicon, etc.)
Monomeric minerals (similar to nesosilicates)
Sulfates (VI) (IDs 7.A–E)
Thiosulphates (IDs 7.J)
Silicate frameworks, tectosilicates
Other tectosilicates (IDs 9.FA. and 9.FB.15, e.g. feldspars )
Other silicate frameworks
Ribbon or multiple chain inosilicates (IDs 9.D, e.g. amphiboles )
Other non monomeric minerals
Unclassified silicates (IDs 9.H)